Вот что то на подобии CSS
#shipping_method_list input:checked ~ * .radio-input {color:red !important}
Т.е. если дочерный input отмечен checked тогда родительский элемент с класом .radio-input {color:red !important}
<div id="shipping_method_list">
<strong class="title nn">Доставка</strong>
<div class="radio-input radio active" id="su.flat.flat">
<label for="flat.flat">
<input type="radio" name="shipping_method" value="flat.flat" id="flat.flat" checked="checked" data-refresh="5" class="styled">
<span class="text">Доставка</span><span class="price">80 руб</span></label>
</div>
<strong class="title nn">Самовывоз</strong>
<div class="radio-input radio" id="su.pickup.pickup">
<label for="pickup.pickup">
<input type="radio" name="shipping_method" value="pickup.pickup" id="pickup.pickup" data-refresh="5" class="styled">
<span class="text">Самовывоз</span><span class="price">0 руб</span></label>
</div>
</div>